• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
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    • 专利摘要:
    SOFT LACE FABRIC This disclosure generally refers to a fabric product that has a lace composition on at least one surface of that material to increase the smoothness of the article, while maintaining or improving manufacturing efficiency. . Preferably, the lace composition comprises a first component, which is cationic, and a second component which is capable of forming a film. Preferably, both the first and the second component are water soluble. The first component has a cationic charge that is capable of forming ionic bonds with the negatively charged fibers of the fabric network, thus providing a retention mechanism in which the lace composition is retained. The general retention of the lace composition reduces the concentration of the composition in the water of the processing machine, increasing its operability and functioning.
    公开号:BR112013025075B1
    申请号:R112013025075-5
    申请日:2012-03-27
    公开日:2021-01-26
    发明作者:Frank Gerald Druecke；Dave Allen Soerens；Benjamin Joseph Kruchoski；Frederick John Lang；Christopher Lee Satori；John Alexander Werner Iv；Cathleen Mae Uttecht；Mickey Joseph Authement Ii
    申请人:Kimberly-Clark Worldwide, Inc.；
    IPC主号:
    专利说明:

    [0001] [1] This form claims the benefit of US Provisional Patent Form No. 61 / 473,601, filed on April 8, 2011, the disclosure of which is hereby incorporated by reference. BACKGROUND OF THE INVENTION
    [0002] [2] Absorption rate, softness and strength are key features for a facial tissue. The rate of absorption of a facial tissue affects its performance in absorbing sneezing and blowing your nose. If the absorption rate is too low, the exhaled content may spread over the face or transfer to other surfaces. In general, tenderness and strength are inversely related in such a way that the reduction in strength will produce an increase in tenderness. There are practical limits to improvements in softness from reduced strength, as the fabric may become too weak for use.
    [0003] [3] Softness can be improved by the topical addition of softening agents, such as a silicone emulsion, to the outer surfaces of the fibrous network. However, softening agents and after-treatment actions can be costly, can increase manufacturing complexity, and can reduce the rate of absorption and strength of the fabric.
    [0004] [4] An alternative to surface treatments is the use of lace (creping) and chemical lace elements (creping) to increase the softness of the fabric. One of these alternatives is described, for example, in US Patent No. 7,883,604, which reveals an increase in the softness of the fabric through the wrinkling (creping) with a water insoluble dispersion that modifies the surface of the fabric net with a thin, intermittent film of polyolefin. Unfortunately, the water insolubility nature of the polyolefin dispersion can negatively impact the functioning of the tissue machine and require a factory wastewater removal system.
    [0005] [5] An alternative to water-insoluble dispersions is described in US Publication No. 2010/0155004, which features a water-soluble wrinkle chemistry comprising a film-forming component and a modifying component. Although these water-soluble wrinkle chemicals eliminate many of the fabric machine's operational challenges, their use requires a removal step to prevent the accumulation of water-soluble chemicals in the plant's hydraulic system.
    [0006] [6] As such, there is currently a need for a creping composition that produces a soft fabric, but is maintained on the sheet without having a negative impact on manufacturing efficiency or requiring additional wastewater treatment. SUMMARY OF THE INVENTION
    [0007] [7] It has been surprisingly discovered that a creping composition containing a cationic element can be added to the fabric sheet during the lace step in the manufacture of a conventional fabric to provide a soft fabric product without negatively impacting the use of the machine. Furthermore, the compositions of the present disclosure can be applied at higher additional levels, for example, the addition in the creping composition rate for the dryer, measured as mass (eg, mg) per unit surface area. dryer (eg m2) is preferably greater than about 50mg / m2. The creping composition provides the added benefit of high leaf retention, such that the leaf has less than about 1% water-soluble extracts. The lace compositions can also be applied to the base sheet in an amount sufficient to increase the softness of the sheet, without negatively impacting the processing and fabrication of the tissue sheet.
    [0008] [8] Therefore, in one aspect, this publication provides a crepe fabric product comprising a crepe fabric network with a fine crepe structure, measured as the coefficient of variation (VOC) at 0.28-0.55 mm, as described in the Test Methods section, or less than 20% VOC; and a fluff greater than 0.95 mm / mm and less than 0.60 percent of water-soluble extracts by weight.
    [0009] [9] In still other aspects, the present disclosure provides a crepe fabric product comprising a crepe fabric weave with a first and a second side: and a crepe composition comprising a cationic component discarded at least on the first side; wherein the fabric web has a thin crepe structure of less than 25% VOC and less than 0.50 percent water soluble extracts by weight of the fabric web.
    [0010] [10] In still other aspects, the present disclosure provides the process for the production of a product sheet that comprises applying a creping composition with a cationic component to a mobile lace surface at levels greater than 50 mg / m2; pressing a base sheet against the lace surface after applying the creping composition; and remove the base sheet from the lace surface.
    [0011] [11] In still other aspects, the present disclosure provides a lacy fabric web comprising a fabric web with a first and a second side, the fabric web having been wrinkled in a rotary dryer to which the creping composition was applied, the lace additive comprising at least two cationic components and a film-forming component. BRIEF DESCRIPTION OF THE DRAWINGS
    [0012] [12] Fig. 1 illustrates a representation of a Yankee dryer used to dry a fibrous web of the present disclosure; Fig. 2 illustrates a configuration for forming wet lacy fibrous networks for use in the present disclosure; and Fig 3 illustrates a part of a fibrous web forming machine, illustrating an aspect of the formation of a stratified fibrous web with multiple layers. DETAILED DESCRIPTION OF THE DRAWINGS
    [0013] [13] The present disclosure relates generally to a fabric product comprising a creping composition placed on at least one surface thereof to increase the softness of the article, while maintaining or increasing manufacturing efficiency. Preferably, the creping composition comprises a cationic component, which, in a particularly preferred configuration, is a water-soluble cationic polymer. The cationic component carries a cationic charge that is capable of forming ionic junctions with the negatively charged fibers in the fabric weave, in addition to providing a retention mechanism in which the creping composition remains retained in the sheet. The general retention of the creping composition on the sheet reduces the concentration of the composition in the water of the processing machine, increasing the machine's operability and functionality. The increased retention also reduces the amount of creping composition in the plant's wastewater, thereby eliminating the need for additional treatment steps. Accordingly, the present disclosure provides a soft fabric product with added high retention, such that only a small amount of the creping composition will dissolve when the product is placed in water, something like less than 0.50 percent of the tissue weight. The high retention of the creping composition is achieved even when it is applied to the Yankee dryer at relatively high additional levels, such as greater than about 50 mg / m2.
    [0014] [14] Without being bound by any particular theory, it is believed that the cationic lace compositions of the present disclosure have a high affinity with the negatively charged cellulose fiber network, producing a network that retains a high percentage of creping composition when moistened. The increased retention of lace chemistry is achieved without negatively affecting other properties of the network. In fact, the network produced according to the present disclosure has lacy structures, Down on the Edge and softness values equal to or greater than networks produced using previous production methods. Thus, once the lace compositions of the present disclosure are applied to the surface of the sheet, the composition is largely retained on the surface, with only a small amount of the composition entering the water of the manufacturing process.
    [0015] [15] In this way, the disclosure provides a creping composition that when applied to a fabric net provides that the mesh is soft and retains a large amount of the composition on its surface, preventing the introduction and accumulation of the creping composition in the water of the manufacturing process. Thus, tissue products of the present invention preferably have water-soluble extracts, making up a weight percentage of less than 1.0%, preferably less than about 0.60%, or even more preferably less than 0.30 %. In a particularly preferable configuration, crepe fabric nets of the present disclosure have from 0.35% to about 0.60% of water-soluble extracts making up the weight of the fabric net. Even more preferable, the aforementioned water-soluble extracts are achieved even when the composition is added to the lace surface, such as a Yankee dryer, at elevated levels such as above 50 mg of composition per square meter of the Yankee dryer surface, being more preferable above about 100 mg / m2, and even more preferable above about 150 mg / m2.
    [0016] [16] While the amount of water-soluble material withdrawn from the fabric items of the present invention is generally expressed as a percentage of the total weight of the fabric item, e.g., percentage of water-soluble extracts, the amount can also be expressed as the mass of water-soluble extracts relative to the area of a single layer of the fabric item. As such, in certain configurations, water-soluble extracts of any single layer of a fabric item prepared in accordance with this publication is preferably less than 150 mg / m2 and even more preferable if less than 100 mg / m2. m2, such as from about 5 to about 50 mg / m2.
    [0017] [17] In order to achieve the desired retention levels, tissue nets are laced using a creping composition that comprises a cationic component. In certain configurations, the cationic component can be a cationic polymer. As used herein, the term "cationic polymer" refers to any polymer containing repeated units selected from cationic groups and groups that can be ionized into cationic groups, the polymer having a charge density greater than 0 milliequivalents per gram of dry polymer . The term "cationic charge density" of a polymer, as used herein, refers to the ratio of the number of positive charges of a polymer to the dry weight of a polymer. The charge density can be measured, for example, by a polyelectrolyte titration using 0.001 N of potassium polyvinyl sulfate as an anionic polymer with a Mutek particle charge detector. Charge density is usually expressed by the number of charge milliequivalents (quaternary nitrogen) per gram of dry polymer (mEq / g). In a particularly preferable configuration, the cationic polymer has a charge density of at least about 0.1 mEq / g, and more preferably from about 0.1 to about 2.0 mEq / g, as well as about 0.2 to about 1.0 mEq / g.
    [0018] [18] In certain configurations, the cationic component may comprise a cationic starch. The term now used "cationic starch" is defined as a starch that has been chemically modified to transmit half of a cationic component. Preferably, the starch is obtained from corn or potatoes, but it can be derived from other sources, such as rice, wheat or cassava. Cationic starches can be divided into the following general classifications: (1) tertiary aminoalkyl ethers, (2) onium starch ethers including quaternary amines, phosphonium and sulfonium derivatives, (3) primary and secondary aminoalkyl starches, and (4) similar ( for example, imino starches). Suitable cationic polymers include cationic starches with a charge density of at least 0.1 mEq / g, such as, for example, RedibondTM 2038 which has a charge density of about 0.22 mEq / g.
    [0019] [19] Cationic starches particularly preferred for use in the lace additive in this publication are tertiary aminoalkyl ethers and quaternary aminoalkyl ethers, which include commercial cationic starches produced by the National Starch and Chemical Company, Bridgewater, NJ, under the trade names RedibondTM and OptiproTM. Levels with only cationic halves such as Redibond 5327TM, Redibond 5330ATM and OptiproTM 650 are suitable, as well as levels with additional anionic functionality such as Redibond 2038TM.
    [0020] [20] In other configurations, the cationic component may comprise a methyl vinylpyrrolidone sulfate / 3-methyl-1-vinillimidazolium, commercially available under the trade name Luvitec QuatTM 73 W; a vinylpyrrolidone / 3-methyl-1-vinylimidazolium chloride, commercially available under the trade name LuviquatTM Style or LuviquatTM Excellence. Other cationic components include polyvinyl amine, commercially available under the trade name LuredurTM. All of these materials are produced by BASF (Florham Park, NJ).
    [0021] [21] The cationic component can be presented in the income composition in any operational quantity and will vary based on the selected chemical component, as well as on the final properties that are desired. For example, in the example case of Redibond 2038TM, the cationic component can be presented in the income composition in a divided amount of about 10-90% by weight, 2080% by weight or 30-70% by weight in relation to total weight of income composition, to provide improved benefits.
    [0022] [22] Among other suitable cationic components, cationic peelers and / or softeners may be included. Cationic detachers and softeners are known in the papermaking activity and are generally used as humidifying additives to increase thickness and softness. Peelers are generally hydrophobic molecules that have a cationic charge. As humidifying additives, peelers typically work by interrupting the interfiber connection, thereby increasing the thickness and noticeably increasing the softness, but at the expense of decreasing the strength of the sheet. Softening agents are similar in chemistry to peelers, for example, they are generally hydrophobic molecules that have a cationic charge. Typically, they are applied to the surface of the paper web by spraying, bonding to the fibers on the surface and providing them with a luscious feel.
    [0023] [23] Examples of chemical peels and softeners may include simple quaternary ammonium salts that have the general formula: (R1 ') 4-b-N + - (R1''') bX- where R1 'is a C1-6 alkyl group, R1 "is a C14-22 alkyl group, b is an integer from 1 to 3 and X- is any suitable counterion. Other similar components may be the monoester, diester , mono starch and diamides derived from simple quaternary ammonium salts A number of variations of these quaternary ammonium compounds must be considered to fall within the scope of the present invention. Commercially available oleic 1-oleyl-amidoethyl-2-imidazole linium as Mackernium CD-183 (McIntyre Ltd., University Park, IL) and Prosoft CP-1003 (Ashland, Inc., Covington, KY).
    [0024] [24] In addition to a cationic component, the lace additives of the present invention may further comprise a second component capable of forming a film when dry, hereinafter referred to as a "film-forming component". Preferably, the film-forming component is water-soluble, although the film-forming component, in particular, may vary, depending on the particular application and the desired result. In one aspect, for example, the film-forming component may be a modified hydroxylpropyl starch, such as GlucosolTM 800 (Chemstar, Minneapolis, MN). An additional film-forming component is poly (ethylene oxide), such as those sold under the trade name PolyoxTM, including at least PolyoxTM N3000 or Polyox N80 (Dow Chemical, Midland, MI). Other suitable film-forming components include cellulose and poly ethers and esters (acrylate esters). Examples of other commercially available film-forming components include methylcellulose (MC), sold under the trade name BenecelTM; hydroxypropylcellulose (HPC), sold under the trade name KlucelTM; and hydroxyethyl cellulose, under the brand name NatrosolTM (all available from Ashland, Inc., Covington, KY). Other suitable film-forming components include polysaccharides of sufficient chain length to form films, such as, but not limited to, pullulan and pectin. The film-forming polymer may also contain additional monoethylenically unsaturated monomers that do not have an acidic pendant group, but which are copolymerizable with monomers with acidic groups. Such compounds include, for example, monoacrylic esters and monomethacryl esters of polyethylene glycol or polypropylene glycol, the molar masses (Mn) of the polyalkylene glycols being around 2000, for example.
    [0025] [25] The film-forming component can be present in the creping composition in any operative amount and will vary based on the chemical component selected, as well as with the final properties that are desired. For example, in the exemplary case of GlucosolTM 800, the film-forming component can be present in the creping composition in a divided amount of about 10-90% by weight, such as 20-80% by weight or 30-70% weight, based on the total weight of the income-forming composition, to provide improved benefits. In the exemplary case of KlucelTM, the film-forming component can be present in the creping composition in an amount of about 1-70% by weight; or at least about 1% by weight; as well as at least about 5% by weight; or at least about 10% by weight; or up to about 30% by weight; such as up to about 50% by weight; or up to about 75% by weight or more, based on the total weight of the income-forming composition, to provide better benefits.
    [0026] [26] In some respects, the film-forming component is dissolved in 1% by weight to about 10% by weight of aqueous solution, and then diluted as needed to provide the desired dosage in mg / m2 of the dryer surface. The dosage is calculated based on the volume of film forming solution multiplied by the concentration of the film forming and divided by the square meters of fabric treated per unit time.
    [0027] [27] In other configurations, the creping composition may also comprise at least one adhesive component capable of adhering the weft to the surface of a dryer. Preferably, the adhesive component is soluble in water and is not crosslinked. The adhesive component contained within the lace-forming composition may vary, depending on the particular application and the desired result. In a preferred embodiment, the adhesive component is the polymerization product of a cationic acrylate or methacrylate and one or more alkyl acrylates or alkyl methacrylates. A preferred adhesive component is a cationic polyacrylate, which is the polymerization product of 96% mol of methyl acrylate and 4% mol of [2 - (acryloyloxy) ethyl] trimethyl ammonium chloride, also referred to here as L7170, which is disclosed in U.S. Patent No. 7,157,389, which is now incorporated in a manner consistent with its disclosure.
    [0028] [28] The adhesive components of the present disclosure may have an average molecular weight that varies according to the end use of the polymer. The adhesive components of the present disclosure have an average molecular weight ranging from about 5,000 to about 500,000 grams per mol. More specifically, the adhesive components of the present disclosure have an average molecular weight ranging from about 8,000 to about 500,000 grams per mol.
    [0029] [29] The adhesive component can be present in the creping composition in any operative quantity and will vary based on the selected chemical component, as well as with the final properties that are desired. For example, in the exemplary case of L7170, the adhesive component may be present in the creping composition in a divided amount of about 10-90% by weight, such as 20-80% by weight, or 30-70% by weight , based on the total weight of the income formation composition, to provide better benefits.
    [0030] [30] In some respects, the adhesive component is dissolved in 1% by weight to about 10% by weight of aqueous solution and then diluted as needed to provide the desired dosage in mg / m 2 of the tissue surface. The dosage is calculated based on the volume of adhesive solution multiplied by the adhesive concentration and divided by the square meters of fabric treated per unit time. For example, in the exemplary case of L7170, the adhesive component can be present in the creping composition, in an amount of about 1-70% by weight; or at least about 1% by weight; such as at least about 5% by weight; or less about 10% by weight; or up to about 30% by weight; such as up to about 50% by weight; or up to about 75% by weight or more, based on the total weight of the income-forming composition, to provide improved benefits. Any of these chemicals, once diluted with water, are placed on a Yankee dryer surface with a spray lance to finally transfer to the weft surface.
    [0031] [31] In one configuration, the creping composition can be applied topically to the network during the lace process. For example, the creping composition can be sprayed onto a heated drying drum in order to adhere the weft to the drying drum. The weft can then be curled from the dryer drum. When the creping composition is applied to the web and then adhered to the drum dryer, the composition can be applied evenly over the surface area of the web, or it can be applied according to a certain pattern. An exemplary curling process is described in U.S. Patent No. 7,883,604, which is incorporated herein by reference, in a form that is consistent with what is presented. A preferred method of lace is illustrated in FIG. 1. In the configuration illustrated in FIG. 1, the creping composition is applied directly to the surface of the dryer 20 (for example, a Yankee dryer) using a spray bar 22, however, other forms of application, such as printing, foaming and cleaning are contemplated. The fibrous web 13 is adhered to the surface of the Yankee dryer, when it is pressed in contact with the composition. The fibrous web and the composition are then scraped from the dryer surface by a lace blade 24.
    [0032] [32] The creping composition provides a fabric with a very fine crepe structure, in which the lace folds are small in frequency and amplitude. This results in a softer and smoother sheet of fabric. In addition to having a thin crepe structure, individual fibers protrude from the fabric surface, while remaining attached. These individual fibers protruding from the surface are called free fiber ends and provide greater smoothness, due to both the imprecision of the fabric surface and the softening of the fibers due to the coating of the creping composition. Evidence for free fiber ends is provided by visual images generated with SEM and the "Fuzz on Edge" test, as described in the Test Methods section. Thus, in certain configurations, the present disclosure provides a fabric web that has a thin crepe structure, measured as a percentage in VOC at 0.28-0.55 mm of less than about 25%, such as about 15% to about 25%, and more preferably from about 18% to about 25%. In other configurations the fabric wefts have a fluff on the upper edge of about 0.90 mm / mm, such as from about 0.90 to about 1.2 mm / mm, and more preferably about 0.95 about 1.1 mm / mm.
    [0033] [33] In addition to having improved surface properties, the fabric prepared according to the present disclosure also has relatively few water-soluble extracts. The cationic components of the creping composition are believed to improve the retention of the creping composition on the surface of the positively charged fiber, preventing the introduction and accumulation of the creping composition in the water of the manufacturing process. Thus, the fabric products of the present invention preferably have water-soluble extracts, expressed as a weight percentage less than about 1.0%, more preferably less than about 0.60%, and even more preferably less than about 0.30%. In a preferable configuration, the lace weft of the present disclosure has between about 0.35% to about 0.60% of water-soluble extracts by weight of the fabric weft.
    [0034] [34] In other configurations, fabric sheets made in accordance with the present disclosure may have a desirable water absorption rate. The water absorption rate of products with cellulose-based fabric affects functional performance. In one example, the tissue for the face must be strong enough in use and also moisten very quickly to absorb liquids, such as a nasal blow. Fabrics generally produced according to the methods disclosed in U.S. Patent No. 7,883,604 have slow absorption times, probably due to the water-insoluble lace chemistry that is transferred to the fabric surface. Compared to conventional lace-forming chemistry and other commercially available competitive fabrics, fabrics produced according to the methods disclosed in U.S. Patent No. 7,883,604 have an absorption time that is at least twice as slow (measured as described below in the Test Methods section), such as greater than about 10 seconds and, in some cases, greater than about 30 seconds. In contrast, the absorption time of the fabrics produced according to certain configurations of the present disclosure is generally less than about 6 seconds. Therefore, in certain configurations, the absorption time can be about 6 seconds or less, more specifically about 5 seconds or less, and more specifically about 2.5 seconds or less.
    [0035] [35] The rate of water absorption can alternatively be measured using the Hercules Size Test (HST). In certain configurations, it may be desirable, from a user's point of view, to have a fabric that is soft, strong enough in use and also wet very quickly in order to absorb liquids, such as runny nose. Thus, the disclosure provides a soft fabric product, with good strength, which also has an HST value of less than about 1.5 seconds, as well as less than about 1 second, for example, about 0, 5 to about 1 second.
    [0036] [36] Compared to commercially available fabrics, the fabric prepared according to the present disclosure generally has a thinner crepe structure, increased fluffiness and faster humidification time, all while having relatively few water-soluble extracts, such as summarized in the table below.
    [0037] [37] In general, any suitable fibrous tissue can be treated in accordance with the present disclosure. For example, in one aspect, the base sheet can be a fabric product, such as a bath tissue, a facial tissue, a paper towel, a napkin, dry and wet wipes, and the like. Fibrous products can be made with any type of suitable fiber. Fibrous products made in accordance with the present disclosure can include fibrous products with a single layer or fibrous products of multiple layers. For example, in some ways, the product may include two layers, three layers, or more.
    [0038] [38] Fibers suitable for making fibrous wefts comprise any natural or synthetic fibers, including coarse and non-coarse fibers or cellulose fibers. Cellulose fibers can be prepared with high yield or low yield methods and can be processed in any known method, including kraft, sulfite, high yield pulping methods and other known pulping methods. Fibers prepared from organosolv pulping methods can also be used, including the fibers and methods disclosed in U.S. Patent Nos. 4,793,898, 4,594,130, 3,585,104. Useful fibers can also be produced by anthraquinone pulping, exemplified by U.S. Patent No. 5,595,628.
    [0039] [39] The fibrous weaves of the present disclosure may also include synthetic fibers. For example, fibrous wefts can include up to about 10%, such as up to about 30% or up to about 50% to about 70% or more of dry weight, to provide improved benefits. Suitable synthetic fibers include rayon, polyolefin fibers, polyester fibers, bicomponent sheath-core fibers, multicomponent bonding fibers, and the like. Types of synthetic cellulose fibers include rayon in all its varieties and other fibers derived from viscose or chemically modified cellulose.
    [0040] [40] Chemically treated natural cellulosic fibers can be used, for example, mercerized pulps, chemically hardened or intercrossed fibers, or sulfonated fibers. To obtain good mechanical properties when using weft forming fibers, it may be desirable for the fibers to be relatively intact and largely unrefined or only slightly refined. While recycled fibers can be used, virgin fibers are generally useful for their mechanical properties and the absence of contaminants. Mercerized fibers, regenerated cellulose fibers, cellulose produced by microbes, rayon, and other cellulosic materials or cellulosic derivatives can be used. Suitable weave forming fibers may also include recycled fibers, virgin fibers, or mixtures thereof.
    [0041] [41] In general, any process capable of forming a frame can also be used in the present disclosure. For example, a weft forming process of the present disclosure can use the wrinkle, moist wrinkle, double wrinkle, wrinkle, double wrinkle, stamping, wet pressing, air pressing, air drying, hydroentangling, air lace drying, co-forming , air laying, as well as other processes known in the area. For the hydroentangled material, the percentage of pulp is around 70-85%.
    [0042] [42] Also suitable for articles of the present disclosure are fibrous sheets that are of a densified or printed pattern, such as, for example, fibrous sheets disclosed in any of the following U.S. Patents Nos. 4,514,345, 4,528,239, 5,098,522, 5,260,171, and 5,624,790, the disclosures of which are hereby incorporated by reference, insofar as they are not contradictory. Such printed fibrous sheets may have a network of densified regions that have been printed against a drum dryer by a printing fabric, and regions that are relatively less densified (for example, "domes" in the fibrous sheet) corresponding to a deflection conduit in the printing fabric, in which the fibrous sheet superimposed on the deflection conduits has been deflected by an air pressure differential through the deflection conduit to form a low-density region similar to cushions or vaulting on the fibrous sheet.
    [0043] [43] The fibrous web can also be formed without a substantial amount of internal fiber-to-fiber bond strength. In this regard, the base fiber used to form the base web can be treated with a chemical peeling agent. The peeling agent can be added to the fiber pulp during the pulping process, or it can be added directly to the inbox. Suitable peeling agents that can be used in the present description include cationic peeling agents, such as dialkylamine quaternary fatty salts, monoalkyl fatty tertiary amine salts, primary amine salts, quaternary imidazoline salts, silicone, quaternary alkyl salts and unsaturated fatty amine salts. Other suitable take-off agents are disclosed in U.S. Patent No. 5,529,665, which is incorporated herein by reference, in a manner consistent with that disclosed.
    [0044] [44] Optional chemical additives can also be added to the aqueous web forming mold or embryonic web formed to add additional advantages to the process and product, and are not antagonistic to the intended benefits of the invention. The following chemicals are included as examples and are not intended to limit the scope of the invention.
    [0045] [45] The types of chemicals that can be added to the paper web include absorption aids, usually in the form of cationic, or nonionic surfactants; humectants and plasticizers, such as low molecular weight polyethylene glycols; and polyhydroxy compounds, such as glycerin and propylene glycol. Materials that provide healthy skin benefits, such as mineral oil, aloe extract, vitamin E, silicone, lotions in general, and the like, can also be incorporated into finished products. Such chemicals can be added at any point in the weft formation process.
    [0046] [46] In general, the products of this disclosure can be used in conjunction with any known materials and chemicals that are not antagonistic in their intended use. Examples of such materials include, but are not limited to, odor control agents, such as odor absorbers, activated carbon fibers and particles, talc, sodium bicarbonate, chelating agents, zeolites, perfumes or other odor masking agents , cyclodextrin compounds, oxidants, and the like. Superabsorbent particles, synthetic fibers, or films can also be used. Additional options include cationic dyes, optical brighteners, humectants, emollients, and the like.
    [0047] [47] Fibrous wefts that can be treated in accordance with the present disclosure may include a single homogeneous layer of fibers or may include a layered or stratified construction. For example, the fibrous weft layer may include two or three layers of fibers. Each layer can have a different fiber composition. For example, with reference to FIG. 3, an aspect of a device for forming a multilayer laminate is illustrated. As shown, the three-layer inbox 10 generally includes an upper inlet box wall 12 and a lower inlet box wall 14. Inbox 10 further includes a first divider 16 and a second divider 19 that separates three layers of stored fibers.
    [0048] [48] Each of the fiber layers comprises a diluted aqueous suspension of fibers to make paper. The particular fibers contained in each layer generally depend on the product to be formed, and on the desired results. For example, the fiber composition of each layer can vary depending on what is being produced, whether a toilet paper product, face cloth products or paper towels. In one aspect, for example, the middle layer 21 contains southern softwood kraft fibers, either alone or in combination with other fibers, such as high yield fibers. Outer layers 23 and 25, on the other hand, contain coniferous wood fibers, such as northern coniferous wood kraft.
    [0049] [49] In an alternative aspect, the middle layer may contain coniferous wood fibers for strength, while the outer layers may comprise wood fibers, such as eucalyptus fibers, for noticeable softness.
    [0050] [50] In general, any process capable of forming a base sheet can be used in the present description. For example, as illustrated in FIG. 3, an endless forming screen 26, suitably supported and driven by rollers 28 and 30, receives the papermaking material from the inbox emission layers 10. Once retained in the fabric 26, the layered fiber suspension water passes through the fabric, as shown by arrows 32. Water removal is achieved by combining the forces of gravity and centrifuge with that of vacuum suction, depending on the formation configuration. The formation of multilayer paper wefts is also described and disclosed in U.S. Patent No. 5,129,988, which is hereby incorporated by reference, in a manner that is consistent with that currently presented.
    [0051] [51] The basis weight of fibrous wefts made in accordance with the present description may vary depending on the final product. For example, the process can be used to produce bath fabrics, facial tissues, paper towels and the like. In general, the base weight of such fibrous products can vary from about 5 g / m2 to about 110 g / m2, as well as between about 10 g / m2 to about 90 g / m2. For toilet papers and facial tissues, for example, the base weight can vary from about 10 g / m2 to about 40 g / m2. For paper towels, on the other hand, the base weight can vary from about 25 g / m2 to about 80 g / m2 or more.
    [0052] [52] Wefts made according to the above processes can have relatively good structural characteristics. For example, the structure of the fibrous web can vary from about 1 to about 20 cm3 / g, such as from about 3 to about 15 cm3 / g, or from about 5 to about 12 cm3 / g. Surprisingly, it has been found that the treatment of paper products with the creping composition of the present disclosure results in fabric products with better structure compared to lace fabric products prepared according to prior art. For example, tissue paper products of the present invention have volumes ranging from about 8 cm3 / g to about 10 cm3 / g. The volumes achieved are from about 10% to about 40% greater than crepe fabric products prepared according to the conventional technique of forming lace with previous wet pressing. The volume increase achieved through the application of the lace forming compositions of the present disclosure can reduce the amount of calendering required during conversion and allow a better volume of fabric such that the volume of the paper product is about 8 cm3 / g about 10 cm3 / g.
    [0053] [53] In multi-layer products, the base weight of each fibrous web present in the product can also vary. In general, the total base weight of a multilayer product will generally be the same as indicated above. In particularly preferred embodiments, the product is a multiple facial tissue where each layer has a basis weight of between about 10 g / m2 to about 20 g / m2 and more particularly between about 12 g / m2 to about 15 g / m2 m2.
    [0054] [54] Now, with reference to FIG. 2, an end box 60 emits an aqueous suspension of fibers in a forming web 62, which is supported and driven by a plurality of guide rollers 64. A vacuum box 66 is arranged below the forming web 62 and is adapted to remove fiber water to aid in the formation of a weave. From the formation of the fabric 62, a formed web 68 is transferred to a second fabric 70, which can be a thread or a felt. The fabric 70 is supported for movement around a continuous path by a plurality of guide rollers 72. Also included is a suspension roller 74 designed to facilitate the transfer of the web 68 from fabric 62 to fabric 70.
    [0055] [55] Preferably the web formed is dried by transferring to the surface of a heated drying drum, such as a Yankee dryer. According to the present disclosure, the creping composition of the present disclosure can be applied topically to the fabric web while the web travels over the fabric or can be applied to the surface of the dryer drum to transfer to one side of the fabric web . In this way, the creping composition is used to glue the weft of the fabric to the drying drum. In this configuration, while the web is transported through a part of the rotation path of the dryer surface, heat is transmitted to the web, causing most of the moisture contained within the web to be evaporated. The weft is then removed from the drying drum by a lace blade. The lace weave, when formed, further reduces the internal weave connection and increases the smoothness. Applying the creping composition to the weft during wrinkling, on the other hand, can increase the weft resistance.
    [0056] [56] In another configuration, the web formed is transferred to the surface of the heated rotary drum dryer, which can be a Yankee dryer. The pressure roller may, in one configuration, comprise a suction pressure cylinder. To adhere the weft to the surface of the drum dryer, a lace adhesive can be applied to the surface of the drying drum by a spray device. The spraying device can emit a creping composition made in accordance with the present disclosure or it can emit a conventional lace adhesive. The weft is adhered to the surface of the drum dryer and then curled into the drum using a lace blade. If desired, the dryer drum can be associated with a cover. The device can be used to force air through or against the web.
    [0057] [57] In other configurations, once woven into the drying drum, the weft can be adhered to a second dryer drum. The second drying drum may comprise, for example, a heated drum surrounded by a cover. The cylinder can be heated from about 25 ° C to about 200 ° C, such as from about 100 ° C to about 150 ° C.
    [0058] [58] To adhere the weft to the second drying drum, a second spray device can pour an adhesive onto the surface of the dryer drum. In accordance with the present disclosure, for example, the second spraying device can discharge a creping composition, as described above. The creping composition not only assists in adhering the fabric web to the drying drum, but is also transferred to the web surface while the web is laced from the drum dryer by the lace blade. After lacing in the second drying drum, the web can optionally be arranged around a cooling scroll drum and cool before being wound on a bobbin.
    [0059] [59] In addition to the application of the creping composition during the formation of fibrous tissue, the creping composition can also be used in post-formation processes. For example, in one aspect, the creping composition can be used during a lace printing process. Specifically, once applied topically to a fibrous fabric, the creping composition is well suited for adhering the fibrous web to a lace surface, such as in a lace printing operation.
    [0060] [60] For example, once a fibrous weave is formed and dried, the lace-forming composition can be applied to at least one side of the weave and that side of the weave can then be laced. In general, the lace formation composition can be applied to only one side of the weave and only one side of the weave can be lace; the creping composition can be applied to both sides of the weft and only one side of the weft is lacy; or the lace forming composition can be applied to both sides of the weft and each side of the weft can be lacy.
    [0061] [61] In one configuration, the lace formation composition can be added to one side of the weave by pleating, using an in-line or offline process. A fabric web made according to the process illustrated in FIG. 2 or FIG. 3, or according to a similar process, is passed through a first lace forming application station, which includes a press made by a soft rubber pressure roller and a gravure pattern roller. The gravure roller is in communication with a reservoir that contains a first lace formation composition. The gravure cylinder applies the creping composition to one side of the web with a preselected pattern. The web is then brought into contact with a heated roller, which can be heated to a temperature of, for example, up to about 200 ° C, and more preferably from about 100 ° C to about 150 ° C . In general, the web can be heated to a temperature sufficient to dry the web and evaporate the water. It should be understood that, in addition to the heated roller, any suitable heating device can be used to dry the weft. For example, in an alternative configuration, the web can be placed in communication with an infrared heater in order to dry the web. In addition to the use of a heated roller or an infrared heater, other heating devices may include, for example, any suitable convection oven or microwave oven.
    [0062] [62] From the heated roll, the weft can be carried by pulling rollers to a second lace forming application station, which includes a transfer roll in contact with a gravure roll, which is in communication with a reservoir containing a second composition of income formation. The second creping composition can be applied to the opposite side of the weft with a pre-selected pattern. The first and second creping composition may contain the same ingredients or may contain different ingredients. Alternatively, the lace compositions can contain the same ingredients in different amounts, as desired. Once the second lace-forming composition is applied, the weft is adhered to a lace roller by a pressure roller and transported on the lace drum surface for a distance and then removed from it by an action. lace blade. The lace sheet carries out a controlled pattern-forming operation on the second side of the lace weave. Although the lace forming composition is applied to each side of the fabric weave, only one side of the weave is subjected to a lace process. It should be understood, however, that in other forms of configuration, both sides of the web may be lacy.
    [0063] [63] Once curled, the lace weave can be pulled through a drying station. The drying station can include any form of heating unit, such as an oven powered by infrared heat, microwave energy, hot air or the like. A drying station may be required in some applications to dry the weft and / or cure the lace formation composition. Depending on the selected lace formation composition, however, in other applications a drying station may not be necessary.
    [0064] [64] The income formation compositions of the present disclosure are usually transferred to the plot at high levels, such that at least about 30% of the income formation composition applied to Yankee is transferred to the plot, more preferably, at least about 45% is transferred, and even more preferably, at least about 60% is transferred. Generally, from about 45% to about 65% of the lace-forming composition applied to the Yankee dryer is transferred to the weft. Thus, the amount of lace additive transferred to the sheet is a function of the amount of lace additive applied to the Yankee dryer. For example, in a 100 mg / m2 spray coverage over the Yankee dryer, it is estimated that about 0.5% of the solids creping composition is incorporated within the fabric web. In a spray coverage of 200 mg / m2 over the Yankee dryer, it is estimated that about 1.0% of the solids in the creping composition is incorporated within the fabric web.
    [0065] [65] The total amount of creping composition applied to each side of the weft can range from about 0.1% to about 10% by weight, based on the total weight of the weft, such as about 0, 3% to about 5% by weight, such as from about 0.5% to about 3% by weight. To achieve the desired levels of additive, the rate of addition of the creping composition to the dryer, measured in mass (ie, mg) per unit of dryer surface area (ie m2), can vary between about 50 mg / m 2 is about 300 mg / m2 and even more preferably about 150 mg / m2 and about 250 mg / m2.
    [0066] [66] In addition, the creping composition is applied to the paper web in order to cover about 15% to about 100% of the surface area of the web. More particularly, in most applications, the creping composition will cover from about 20% to about 60% of the surface area on each side of the web.
    [0067] [67] In one aspect, fibrous webs made in accordance with the present disclosure can be incorporated into multilayer products. For example, in one aspect, a fibrous web made in accordance with the present disclosure can be linked to one or more other fibrous webs to form a cleaning product with the desired characteristics. The other wefts laminated to the fibrous weave of the present disclosure can be, for example, a wet lace weave, a calendered net, a raised weave, a dry weave by air, a lace weave by air, a weave laced by crossing air, an airlaid weave, and the like.
    [0068] [68] In one aspect, when incorporating a fibrous web made according to the present disclosure into a multilayer product, it may be desirable to apply the lace-forming composition to only one side of the fibrous web and then to wrinkle the treated side. of the plot. The lacy side of the weft is then used to form an outer surface of a multilayer product. The untreated and untied side of the weft, on the other hand, is fixed by any means suitable for one or more layers. TEST METHODS Water-soluble extracts
    [0069] [69] The term "water-soluble extracts" refers to the amount of material in a tissue sheet that dissolves in water and can be expressed as a percentage by weight of the tissue sheet or a weight per unit area of the tissue sheet (mg / m2 or g / m2). Multilayer fabrics can be separated into individual layers and the water-soluble extracts determined for each layer. If the sheets have the same composition, the water-soluble extracts measured using the multilayer tissue sheet can then be divided by the equivalent number of layers.
    [0070] [70] The area of a 1-2 gram sample of the tissue sheet to be tested is measured; it is then weighed on an analytical balance as close to 0.0001g, and finally placed in a 100 ml collection container. Fifty milliliters of deionized water at room temperature are added to the collection container (VWR Specimen Container, Catalog No. 25384-148). The collection vessel is sealed and stirred on a table shaker at 150 rpm for one hour. After removal, the sample is vacuum filtered using a Coors Buchner porcelain funnel (87 mL capacity) containing a Whatman 934-AH microfiber glass filter (Whatman catalog No 1827-042, Whatman Inc., GE Healthcare , www.whatman.com) and a 125 mL filter bottle. All contents of the cup are transferred to the filter with forceps. The collection container is rinsed twice with about 10 mL of deionized water and poured over the tissue in a funnel.
    [0071] [71] The tissue in the funnel is then washed with 5 ml of deionized water, flipped with forceps, and washed with an additional 5 ml of deionized water. The tissue in the funnel is then compressed, using the plunger of a disposable syringe to release the absorbed water. The extract (filtered) is transferred to a 100 ml tare cylinder. The filter flask is rinsed twice with 10 ml of deionized water and added to the extract in the beaker. The total volume in the beaker is close to 100 mL. The beaker is dried in an oven at 105 ° C for 18 hours, cooled, and weighed.
    [0072] [72] The percentage of water extracts (% WSE) is calculated from the weight of the fabric and the tare and the final weight of the beaker.
    [0073] [73] Water extracts in mg / m2 are calculated using the percentages of water-soluble extracts and the base weight of the tissue sheet tested.
    [0074] [74] Three tests are performed per sample. The average percentage of water-soluble extracts and the average of water-soluble extracts (mg / m2) are reported for each sample. Absorption Rate Test
    [0075] [75] The "Absorption Rate Test (Humidification Time)" is used to determine the absorption time ("Humidification Time"). To perform the test, the test product is first equilibrated in ambient conditions for at least four hours at 23 ± 3.0 ° C and 50 ± 5% relative humidity. Twenty (20) sheets are stacked and cut into 60 x 60 mm (± 3mm) squares using a device capable of cutting to the specified dimensions, such as a Hudson machine. Each square is then fixed to a corner by staples provided by a standard, commercially available manual office stapler. The staples are placed diagonally at each corner, deep enough in the sheet so that the staples are completely contacting the tissue sheets, staples should not wrap around the sample corner. The sample is then placed horizontally and about 25 mm (1 inch) over a container containing distilled or deionized water at 23.0 ± 3.0 ° C. The container must be of sufficient size and depth to ensure that the saturated sample does not come into contact with the walls, the bottom of the container, or the upper surface of the water at the same time. The container must include a minimum depth of 51 mm of water to ensure complete saturation of the test sample and this depth must be maintained throughout the test. The sample is then placed on the water surface and a timing device is started when the sample comes in contact with the water surface. As soon as the sample is completely saturated, the timing device is stopped and the absorption time in seconds is recorded. Fuzz on Edge
    [0076] [76] The Fuzz on Edge methodology measures the amount of fibers that protrude from the surface of a fibrous material. The measurement is performed by means of image analysis to detect and measure the total perimeter of the fibers protruding from the surface observed when the material in question is surrounded by an "edge" that allows the fibers to be seen from the side using transmitted light. An image analysis algorithm has been developed to detect and measure the perimeter length (mm) of the fibers per unit length (mm) of the material, where the perimeter length is defined as the total length of the boundaries of all protruding fibers. (ie Perimeter / Edge Length or PR / EL, in abbreviations). For example, an edge along most of the length of a fibrous material (eg, facial tissue) can be measured by acquiring and analyzing multiple adjacent fields of view, to arrive at a single PR / EL value. Typically, several of these material species are analyzed so that a sample reaches a significant PR / EL value.
    [0077] [77] Fuzz on Edge has been determined using the method described in US Publication No. 2010/0155004 with the following modifications. The Leica DFX-300 camera (Leica Microsystems Ltd, Heerbrugg, Switzerland) is mounted on a standard support of a Polaroid MP-4 Land Camera (Polaroid Resource Center, Cambridge, MA). The holder is attached to a Kreonite macro observer (Kreonite, Inc., Wichita, KS). An autophase, ICD Model HM-1212, is placed on the top surface of the Kreonite macro observer and the sample mounting apparatus is placed on top of the autophase (commercially available from Components Design Incorporated, Franklin, MA). The autophase is used to move the sample in order to obtain 15 images of the specimen, which do not overlap, and are separate and distinct. The sample assembly device is placed over the auto macro phase (DCI 12x12 cm) of an image analysis system controlled by Leica Microsystems' QWIN Pro software, under the optical axis of a 60 mm lens from Nikon Micro AF (Nikon Corp, Japan) equipped with a 20 mm extension tube. The lens focus is adjusted to provide maximum magnification and the position of the camera on the Polaroid MP-4 holder is adjusted to provide optimum focus from the edge of the fabric. The sample is illuminated under the autophase using a Pro Chroma 45 (Circle 2, Inc., Tempe, AZ). The settings of the Chroma Pro are such that the light is "white" and unfiltered, so as not to impair the spectral output of the light. The Chroma Pro can be connected to a POWERSTAT variable autotransformer, type 3PN117C, which can be purchased from Superior Electric, Co. which has an office in Bristol, CT. The autotransformer is used to adjust the lighting level of the Chroma Pro. Crepe Structure Analysis
    [0078] [78] To determine the structure of the tissue sheet after wrinkling, the crepe structure was characterized using tissue images and in the STFI staining program as described in US Publication No. 2010/0155004, with the following modifications. The STFI staining program was written to run with Matlab computing and programming software. A grayscale image is loaded into the program, where an image of the fabric in question was generated under controlled, low-angle lighting conditions with a video camera, capture card and an image acquisition algorithm.
    [0079] [79] A Leica DFX-300 camera (Leica Microsystems Ltd, Heerbrugg, Switzerland) 420 is mounted on a standard 422 mount of a Polaroid MP-4 Land Camera (Polaroid Resource Center, Cambridge, MA). Support is attached to a Kreonite macro observer available from Kreonite, Inc., with an office in Wichita, KS. A Model HM-1212 DCI autophase is placed on the top surface of the Kreonite macro observer and the sample mounting apparatus is placed on top of the autophase. The autophase is a motorized device known to experts in the analytical field that is purchased from Design Components Incorporated (ICD), with an office in Franklin, MA. The autophase is used to move the sample in order to obtain 15 images of the specimen that do not overlap, are separate and distinct. The sample mounting device 424 is placed over the auto macro phase (DCI 12x12 cm) in an image analysis system controlled by Leica Microsystems QWIN Pro software, under a 60 mm optical axis of a Nikon Micro AF lens (Nikon Corp, Japan) equipped with a 20 mm extension tube. The lens focus is adjusted to provide maximum magnification and the position of the camera on the Polaroid MP-4 holder is adjusted to provide better focus from the edge of the fabric. The sample is illuminated under the autophase using a Pro Chroma 45 (Circle 2, Inc., Tempe, AZ). The settings of the Chroma Pro are such that the light is "white" and unfiltered so as not to impair the spectral output of the light. The Chroma Pro can be connected to a variable POWERSTAT autotransformer, type 3PN117C, which can be purchased from Superior Electric, Co. which has an office in Bristol, CT. The autotransformer is used to adjust the lighting level of the Chroma Pro. The result of the image has a pixel resolution of 1024 x 1024 and represents a field of view of 12.5 mm x 12.5 mm.
    [0080] [80] The image analysis system used for the PR / EL measurement can be a QWIN Pro (Leica Microsystems, Heerbrugg, Switzerland). The system is controlled and run by QWIN Pro software version 3.2.1. The image analysis algorithm 'FOE3a' is used to acquire and process monochrome images in shades of gray using the language of the Quantimet Interactive User Interaction Programming System (QUIPS). Alternatively, the FOE3a program could be used with the latest QWIN Pro platforms that run newer versions of the software (for example, QWIN Pro version 3.5.1). The image analysis program was previously described in US Publication No. 2010/0155004.
    [0081] [81] The STFI staining software analyzes the gray scale variation of the image, both in the MD and CD instructions, using the FFT (Fast Fourier Transform). The FFT is used to develop grayscale images at different wavelengths based on the frequency information present in the FFT. The gray scale coefficient of variation (VOC%) is then calculated from each of the images (for example, inverse of the FFT) corresponding to the wavelengths that were predetermined by the STFI software. Since these images are generated with low angle lighting, the surface structure of the fabric is shown as areas of light and dark, due to the shading, and, consequently, the variation of gray tones can be related to the structure of the surface of the fabric. tissue. For each code, three fabrics are analyzed with six images of each fabric, resulting in a total of 18 images analyzed per code. HST
    [0082] [82] The "Hercules Size Test" (HST) is a test that usually measures how long it takes for a liquid to pass through a sheet of tissue. The Hercules size test was done entirely in accordance with the TAPPI T 530 PM-89 method, paper size test with ink resistance. Hercules size test data were collected on a model HST tester using white and green calibration tiles and the black disc provided by the manufacturer. A 2% naphthol green dye diluted in 1% distilled water was used as the dye. All materials are available from Ashland, Inc., Covington, KY.
    [0083] [83] Six (6) sheets of tissue (18 layers of tissue for a three-layer product, 12 layers for a two-layer product, 6 layers for a single-layer product, etc.) form the test specimen. All specimens were conditioned for at least 4 hours at 23 ± 1 ° C and 50 ± 2% relative humidity before testing. The specimens are cut to approximately 6.35 x 6.35 centimeters (2.5 x 2.5 inches). The specimen (12 layers of tissue for a two-layer product) is placed in the sample holder, with the outer surface of the layers facing outward. The sample is then stapled to the sample holder. The sample holder is then positioned on the retaining ring at the top of the optical housing. Using the black disk, the zero instrument is calibrated. The black disc is removed and 10 ± 0.5 mm of dye solution is dispensed from the retaining ring and the timer is started the moment the rear of the disc is placed over the sample. The test time in seconds (sec.) Is recorded by the instrument. EXAMPLES Example 1
    [0084] [84] Inventive sample codes were made using a wet pressure process using a Crescent Former. Initially, the northern softwood kraft (NSWK) paste was placed in a pulper, for 30 minutes at 4% consistency at about 100 ° F (37.7 ° C). The NSWK pulp was then transferred to a dump box and subsequently diluted to approximately 3% consistency. NSWK pulp was refined at 5.2 hp-days / metric ton. The amount of softwood fibers was evenly divided and added to the middle and side felt layers in the three-layer fabric structure. The virgin fiber content NSWK contributed about 30-40% of the final weight of the sheet. 1.8-2 kg Kymene® 920A and 0.9-1.1 kg Baystrength 3000 (Kemira, Kennesaw, GA) per ton of wood fiber were added to the NSWK pulp prior to the arrival box.
    [0085] [85] Aracruz ECF, an eucalyptus Kraft wood pulp (EHWK) (Aracruz, Rio de Janeiro, RJ, Brazil) was dispersed in a pulper for 30 minutes at about 4% consistency at about 100 ° F (37 , 7 ° C). The EHWK pulp was then transferred to a dump box and subsequently diluted to about 3% consistency. EHWK pulp fibers were added to all three layers of the three-layer fabric structure. Only EHWK pulp fibers were added to the drying layer of the three-layer structure, the drying layer represented 40% of the weight of the final sheet. The rest of the EHWK pulp fibers were equally divided between the medium and the felt layers. The EHWK layers contributed approximately 60-70% of the weight of the final sheet. 1.8-2 kg Kymene ® 920A per ton of wood fiber was added to the EHWK pulp before the arrival box.
    [0086] [86] The pulp fibers from the machine boxes were pumped into the inbox with a consistency of about 0.1%. Pulp fibers from each machine box were sent through separate collectors in the arrival box to create a three-layer fabric structure. The fibers were deposited on felt using a Crescent Former.
    [0087] [87] The wet sheet, about 10-20% of consistency, was adhered to a Yankee dryer, going to about 4,600 fpm (1400 mpm) through a nip with a pressure roller. The consistency of the wet sheet after pressing the pressure roller (post-pressure roller consistency or PPRC) was approximately 40%. The wet sheet is adhered to the Yankee dryer due to the additive composition that is applied to the dryer surface. A spray bar located under the Yankee dryer sprayed the creping / additive composition, described in the present disclosure, on the surface of the dryer at additional levels ranging from 150 to 200 mg / m2.
    [0088] [88] The lace forming compositions of GlucosolTM 800, RedibondTM 2038A, and ProsoftTM TQ1003 that were applied to the Yankee dryer were prepared by diluting the polymer solutions in water, followed by stirring until the solution was homogeneous. Each polymer was dissolved or diluted, and pumped separately into the process. GlucosolTM 800 and ProsoftTM TQ1003 were prepared at about 6% solids. RedibondTM 2038A was prepared at 15% solids. The flow rates of GlucosolTM 800, RedibondTM 2038A, and ProsoftTM TQ1003 solutions were varied to provide a total addition of 150 to 200 mg / m2 of spray coverage over the Yankee dryer, in the desired component ratio.
    [0089] [89] The sheet was dried at about 98-99% consistency as it moved over the Yankee dryer and the lace blade. The lace blade then scraped the fabric sheet and a portion of the additive composition out of the Yankee dryer. The base sheet of the creped fabric was then wound into a core traveling at about 3,600 fpm (1100 mpm) in soft rolls for conversion. The base sheet of the resulting fabric has a dry air base weight of about 14.2 g / m 2. Two soft rolls of the creped fabric were then rewound, calendered and stacked together so that both sides were outside the 2-layer structure. Mechanical sticking on the edges of the structure kept the layers together. The sheet was then cut at the edges to a standard width of about 21.59 centimeters (8.5 inches), and cut to the size of facial tissue. The tissue samples were conditioned and tested. Table 2
    [0090] [90] In other cases, inventive sample codes were made using a wet pressing process using a Crescent Former. Initially, northern softwood kraft pulp (NSWK) was dispersed in a pulper for 30 minutes at 4% consistency at about 100 ° F (37.7 ° C). The NSWK pulp was then transferred to a dump box and subsequently diluted to about 3% consistency. NSWK pulp was refined at 1.5-5.0 hp-days / metric ton. The soft wood fibers were used as the inner strength layer in a triple layer fabric structure. The NSWK layer contributed about 34-38% of the final weight of the sheet. Two kilograms of Kymene ® 920A and 1-5 kg Hercobond ® 1366 (Ashland, Incorporated, Covington, KY) per ton of wood fiber were added to the NSWK pulp prior to the arrival box.
    [0091] [91] Aracruz ECF, an eucalyptus Kraft wood pulp (EHWK) (Aracruz, Rio de Janeiro, RJ, Brazil) was dispersed in a pulper for 30 minutes at about 4% consistency at about 100 ° F (37 , 7 ° C). The EHWK pulp was then transferred to a dump box and subsequently diluted to about 3% consistency. EHWK pulp fibers were used in the two outer layers of the triple layer fabric structure. The EHWK layers contributed about 62-66% of the final weight of the sheet. Two kilograms of Kymene ® 920A per ton of wood fiber were added to the NSWK pulp before the arrival box.
    [0092] [92] The cellulose fibers from the machine boxes were pumped to individual fan pumps which subsequently pumped the fibers to the inbox, while diluting the product flows to a consistency of about 0.1%. Pulp fibers from each machine box were sent via pumps with separate fans and subsequently into distribution tubes in the arrival box to create a triple layer fabric structure.
    [0093] [93] The lace forming compositions of GlucosolTM 800, RedibondTM 2038A, ProsoftTM TQ1003 and PolyoxTM N80 that were applied to the Yankee dryer were prepared by dissolving the solid polymers in water, followed by stirring until the solution was homogeneous. Each polymer was dissolved and pumped separately to the process. GlucosolTM 800 and ProsoftTM TQ1003 were prepared at 5% solids. PolyoxTM N80 was prepared at 2% solids. RedibondTM 2038A was prepared at 2-6% solids. Flow rates for GlucosolTM 800, RedibondTM 2038A and ProsfotTM TQ1003 and PolyoxTM N80 solutions varied to provide a total of additional 50 to 1000 mg / m2 of spray coverage in the Yankee dryer at the desired component ratio.
    [0094] [94] The sheet was dried at about 98-99% consistency as it moved over the Yankee dryer and the lace blade. The lace blade subsequently scraped the fabric sheet and a portion of the creping composition out of the Yankee dryer. The lacy base fabric was then wrapped in a core, traveling at about 1570 to about 3925 fpm (480 mpm at 1200 mpm) in soft rolls for conversion. The base sheet of the resulting fabric has a dry air base weight of about 14.2 g / m 2. Two soft rolls of the creped fabric were then rewound, calendered and handled together so that both sides were outside the double-layered structure. A mechanical nailing on the edges of the structure held the layers together. The sheet was then cut at the edges to a standard width of about 21.59 centimeters (8.5 inches) and folded and cut to the size of facial tissue. The tissue samples were conditioned and tested.
    [0095] [95] Additional inventive and control codes have been prepared according to the process illustrated in FIG. 2. Initially, the northern softwood kraft (NSWK) pulp was dispersed in a pulper for 30 minutes at 1.6% consistency at about 100 ° F (37.7 ° C). NSWK pulp was refined with a refiner inserted into the pulper for 3 to 15 minutes. NSWK pulp was then transferred to a machine box and subsequently diluted to approximately 0.27% consistency. The soft wood fibers were used as the inner strength layer in a triple layer fabric structure. The NSWK layer contributed about 30-32% of the final leaf weight. Two kilograms of KymeneTM 920A (12.5% solids) per ton of wood fiber were added to the NSWK pulp before the arrival box in the machine body.
    [0096] [96] Aracruz ECF, an eucalyptus Kraft wood pulp (EHWK) (Aracruz, Rio de Janeiro, RJ, Brazil) was dispersed in a pulper for 30 minutes at about 1.6% consistency at about 100 ° F (37.7 ° C). The EHWK pulp was then transferred to a dump box and subsequently diluted to about 0.14% consistency. EHWK pulp fibers were used in the two outer layers of the triple layer fabric structure. The EHWK layers contributed about 68-70% of the final weight of the sheet.
    [0097] [97] The cellulose fibers from the machine boxes were pumped into the inbox with a consistency of about 0.02%. Pulp fibers from each machine box were sent through separate collectors in the arrival box to create a tri-layer fabric structure. The fibers were deposited on a fourdrenier type felt as shown in figure 2.
    [0098] [98] The wet sheet, with a consistency of about 10-20%, was passed through the narrowing of a pressure roller, partially dehydrating the sheet to a consistency of about 40%. The wet sheet was then attached to the Yankee dryer by spraying the creping composition onto the dryer surface using a lance located under the dryer.
    [0099] [99] Lace additives were prepared by dissolving the solid polymers in water, followed by stirring until the solution was homogeneous. As described above, the polymers were diluted through the spray coating in the Yankee dryer in the desired proportion of the component. The variation in the flow rates of the polymer solution also varies the amount of solids incorporated in the base web. The sheet was dried at about 98-99% consistency as it moved over the Yankee dryer and the lace blade. The lace blade subsequently scraped the fabric sheet and a portion of the creping composition out of the Yankee dryer. The base sheet of the creped fabric was then wrapped in a core traveling from about 47 to about 52 fpm (15 mpm to 17 mpm) in soft rolls for conversion. The base sheet of the resulting fabric had a dry air base weight of about 14 g / m 2 (gsm). The soft rolls were then rewound, calendered and handled together so that both creped sides were outside the double-layered structure.
    [0100] [100] Additional samples were also prepared using water-soluble lace chemicals as previously described in US Publication No. 2010/0155004. The codes of the samples prepared using the prior art of water-soluble lace chemicals are summarized below.
    [0101] [101] The tissue samples prepared as described above were subjected to physical tests, the results of which are summarized in the tables below. Table 6
    [0102] [102] These and other modifications and variations of the present disclosure can be practiced by those skilled in the art, without departing from the spirit and scope of the present disclosure, which is defined, more particularly, in the appended claims. In addition, it should be understood that aspects of the various configurations can be exchanged both in whole and in part. In addition, those skilled in the art will understand that the above descriptions are by way of example only, and are not intended to limit the invention described in the appended claims.
    权利要求:
    Claims (17)
    [0001]
    Crepe fabric product, characterized by comprising a crepe fabric weave having a fine crepe structure, measured as% VOC on a STFI wavelength of 0.28 to 0.55 mm, less than 20% VOC, a fluff on the edge (Fuzz on Edge) greater than 0.95 mm / mm and less than 0.60 percent of water-soluble extracts by weight of the fabric weft.
    [0002]
    Crepe fabric product according to claim 1, characterized in that the crepe fabric weave has a dry basis weight of 24 to 28 g / m2 and a specific volume of 10 to 12 cm3 / g.
    [0003]
    Crepe fabric product according to claim 1, characterized by the fact that it has a Hercules Size Test (HST) value of less than 1 second.
    [0004]
    Crepe fabric product according to claim 1, characterized by the fact that it has a humidification time of less than 3 seconds.
    [0005]
    Crepe fabric product according to claim 1, characterized in that the fabric product contains several individual sheets of fabric, which are in a stacked arrangement.
    [0006]
    Crepe fabric product according to claim 1, characterized in that the fabric product contains several sheets of fabric wound in a spiral together, each of the sheets of fabric being separated by a line of weakness.
    [0007]
    Crepe fabric product according to claim 1, characterized in that the crepe fabric weave has from 0.35 to 0.60 percent water soluble extracts by weight of the fabric weave.
    [0008]
    Crepe fabric product according to claim 1, characterized in that the crepe fabric weave has a fine crepe structure, measured as% VOC at an STFI wavelength of 0.28 to 0.55 mm, from 18 to 20 percent VOC, a fluff on the edge (Fuzz on Edge) of 0.95 to 1.2 mm / mm and 0.2 to 0.5 percent of water-soluble extracts by weight of the fabric weft.
    [0009]
    Crepe fabric web, characterized by having a first side and a second side, and a creping composition comprising at least one cationic component disposed on at least the first side of the fabric on which the fabric web has a crepe structure thin, measured as% VOC on an STFI wavelength of 0.28 to 0.55 mm, less than 25 percent VOC, a fuzz on the edge (Fuzz on Edge) greater than 0.90 mm / mm and less 1 , 0 percent of water-soluble extracts by weight of the fabric weft.
    [0010]
    Crepe weft according to claim 9, characterized in that the creping composition is soluble in water.
    [0011]
    Crepe fabric web according to claim 9, characterized in that at least one cationic component comprises an amphoteric starch or a cationic starch with a charge density of at least 0.1 mEq / g.
    [0012]
    Crepe weft according to claim 9, characterized by the fact that the at least one cationic component comprises a quaternary ammonium salt having the general formula: (R1 ') 4-b-N + - (R1''') bX- where R1 'is a C1-6 alkyl group, R1''is a C14-22 alkyl group, b is an integer from 1 to 3 and X- is any suitable counterion.
    [0013]
    Crepe fabric web according to claim 9, characterized by the fact that the at least one cationic component comprises a cationic oleic imidazoline.
    [0014]
    Crepe fabric web according to claim 9, characterized in that the creping composition additionally comprises a film-forming component selected from the group consisting of modified hydroxylpropyl starch, poly (ethylene oxide), cellulose ethers and esters and poly (acrylate esters).
    [0015]
    Crepe fabric web according to claim 9, characterized in that the creping composition further comprises an adhesive component selected from the group consisting of polyethylene glycols, ethylene glycols terminated in amines, and ethylene glycol block copolymers - propylene glycol.
    [0016]
    Crepe fabric web according to claim 9, characterized in that the creping composition comprises at least two different cationic components and a film-forming component placed on at least the first side.
    [0017]
    Crepe fabric weave, according to claim 16, characterized by the fact that the first cationic component is a cationic starch, the second cationic polymer has the general formula: (R1 ') 4-b-N + - (R1''') bX- wherein R1 'is a C1-6 alkyl group, R1''is a C14-22 alkyl group, b is an integer from 1 to 3 and X- is any suitable counterion; and the film-forming component is selected from the group consisting of modified hydroxylpropyl starch, poly (ethylene oxide), cellulose and poly ethers and esters (acrylate esters).
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    同族专利:
    公开号 | 公开日
    MX360081B|2018-10-19|
    IL228385D0|2013-12-31|
    EP2694734B1|2017-08-16|
    AU2012241009A1|2013-10-03|
    BR112013025075A2|2017-02-14|
    KR101448416B1|2014-10-07|
    WO2012137102A2|2012-10-11|
    KR20140008419A|2014-01-21|
    AU2012241009B2|2014-06-12|
    EP2694734A2|2014-02-12|
    US20120255693A1|2012-10-11|
    US8679295B2|2014-03-25|
    MX2013011390A|2015-07-17|
    WO2012137102A3|2012-12-27|
    EP2694734A4|2014-11-19|
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    法律状态:
    2017-02-21| B15I| Others concerning applications: loss of priority|
    2017-05-30| B12F| Appeal: other appeals|
    2018-09-18| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2020-08-04| B07A| Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]|
    2020-12-08| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2021-01-26| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 27/03/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    US201161473601P| true| 2011-04-08|2011-04-08|
    US61/473,601|2011-04-08|
    US13/424,652|US8679295B2|2011-04-08|2012-03-20|Soft creped tissue|
    US13/424,652|2012-03-20|
    PCT/IB2012/051466|WO2012137102A2|2011-04-08|2012-03-27|Soft creped tissue|
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